1,2,3-triazole based metal-organic framework as photo-active materials

ABSTRACT

A TAF compound that can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF compound can be 
     
       
         
         
             
             
         
       
     
     wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y 1 , Y 2 , Y 3 , Y 4 , and Y 5  can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z 1 , Z 2 , Z 3 , Z 4 , and Z 5  can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives. Included is a preparation of the TAF compound and use as a photoactive and/or catalyst.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority to provisional application numbered 61/395,341 filed on May 12, 2010.

REFERENCE TO SEQUENCE LISTING, A TABLE, OR A COMPUTER PROGRAM LISTING COMPACT DISC APPENDIX

Not Applicable

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

FIG. 1 is a representative structure of the ligand design and modification.

FIG. 2 is the reaction for TAMOF production.

DETAILED DESCRIPTION OF THE INVENTION

A first embodiment can be triazole-modified compound TAF. The TAF compound can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF. The TAF compound can be

wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y¹, Y², Y³, Y⁴, and Y⁵ can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z¹, Z², Z³, Z⁴ and Z⁵ can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives.

TAF can be prepared from bifunctional 1,2,3-triazoles by treatment with Zn(NO₃)₂. About 1-5 mmol of the 1,2,3-triazole solutions wherein the solvents can be water, acetonitrile, DMSO, DMF, DEF, any alcohol, THF. This solution can be added to about 1-5 mmol Zn(NO₃)₂ solutions at a concentration between about 0.1 mmol to about 2 mol wherein the solvents can be water, acetonitrile, DMSO, DMF, DEF, any alcohol, THF. The solutions can be kept at an effective temperature which can range from about room temperature to about 180° C. for an effective time from about 1 hour to about 7 days to prepare TAF.

FIG. 2 details the TAMOF preparation. The Zn2+coordination sites are on the COOH sites of the tirazole while the Ns provide photoactive triazole linkers with good stability and unique photoelectronic properties.

The TAF compound can be used as a photoactive material and/or catalyst. The absorption wavelength could be easily adjusted by the substitution of different aryl groups such as F; CN, Cl, OMe, phenyl, or heteroaromatic structures on the TAF compound. The N-aryl triazoles possess unique molecular orbital distributions. This feature makes the preparation of solar-light absorbing linkers for the preparation of metal-organic frameworks feasible. The orbital distribution made triazole one unique compound to express interesting photo and electronic properties. TAF has a band gap around 2.8 eV which is optimal for a photocatalysis as seen in FIG. 1. The HOMO and LUMO were confirmed locating on the triazole ring and H-bonding between C-4-H and CO₂ was revealed with a calculated 17 kcal/mol of binding energy.

These terms and specifications, including the examples, serve to describe the invention by example and not to limit the invention. It is expected that others will perceive differences, which, while differing from the forgoing, do not depart from the scope of the invention herein described and claimed. In particular, any of the function elements described herein may be replaced by any other known element having an equivalent function. 

1. A compound comprising

wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl, any substituted alkyl group, ketone, aldyhyde, or carboxylic acid derivative, Y¹, Y², Y³, Y⁴, and Y⁵ can be one or more of H, aromatic groups, hetero aromatic groups, alkyl, any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivative, and Z¹, Z², Z³, Z⁴ and Z⁵ can be one or more of H aromatic groups, hetero aromatic groups, alkyl, any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivative.
 2. A method comprising preparing a TAF compound from bifunctional 1,2,3-triazoles with Zn(NO₃)₂ treatment wherein about 1-5 mmol of the bifunctional 1,2,3-triazoles in solution can be added to about 1-5 mmol of Zn(NO₃)₂ in solution at wherein the Zn(NO₃)₂ can be between about 0.1 mmol to about 2 mol in concentration wherein the solvents for the bifunctional 1,2,3-triazoles and the Zn(NO₃)₂ can be one or more of water, acetonitrile, DMSO, DMF, DEF, an alcohol, and THF and the solutions are kept at an effective temperature for an effective time to prepare the TAF.
 3. The method of claim 2 wherein the effective temperature is from about room temperature to about 180° C.
 4. The method of claim 2 wherein the effective time is from about 1 hour to about 7 days. 